Nomenclature means the system of naming of organic compounds.In case of aliphatic compounds, two system of nomenclature generally used are:
1) Trivial or common system
2) IUPAC system
Trivial or common system
Organic compounds were named after the source from which they were first isolated.
For example : Urea got its name since the compound was first obtained from the urine of mammals.
Methyl alcohol was called wood spirit since it could be obtained by the destructive distillation of wood.
Acetic Acid got its name from the acetum since it is present in vinegar.
Formic acid was derived from formicus since it could be obtained by the destructive distillation of red ants.
Citric acid is named so because it is found in citrus fruits.
Common or Trivial names of some organic compounds:
|CH3CH2OCH3||Ethyl Methyl ether|
To systematize the nomenclature of organic compounds, IUPAC system of nomenclature was first introduced in 1947.
General rules for IUPAC Nomenclature of organic compounds
The most important feature of this system is that any given molecular structure has only one IUPAC name and any given IUPAC name denotes only one molecular structure.
The IUPAC name of any organic compound essentially consist of three parts ,i.e.
1) word root
It denotes the number of carbon atoms present in the parent chain (the longest possible continuous chain of carbon atoms including the functional group and multiple bonds) of the organic molecule.
|Chain Length||Word Root|
There are two types of suffix :
1) Primary suffix : A primary suffix is always added to the word root to indicate whether the carbon chain is saturated or unsaturated.
The three basic primary suffixes are :
|Type of carbon chain||Primary suffix||General name|
|Unsaturated with one double bond||-ene||Alkene|
|Unsaturated with one triple bond||-yne||Alkyne|
If the parent chain contains two, three, four or more double or triple bonds ,numerical prefixes such as di, tri ,tetra are added to the prefect primary.
|Type Of carbon chain||Primary Suffix||General name|
|Unsaturated with two double bonds||-diene||Alkadiene|
|Unsaturated with two triple bonds||-diyne||Alkadiyne|
2) Secondary suffix : A secondary suffix is then added to the primary suffix to indicate the nature of the functional group present in the organic compound.
|Class of Organic compound||Functional Group||Secondary Suffix|
|carboxylic acid||-COOH||-oic acid|
|Acid chloride||-COCl||-oyl chloride|
While adding the secondary suffix to primary suffix ,the terminal e of the primary suffix is dropped if the secondary suffix begins with a vowel but is retained if the secondary suffix begins with a consonant.
1) Locants are placed immediately before the part of the name to which they relate.
For Ex : But-2-ene , Propan-2-ol
2) The locant 1 is often omitted when there is no ambiguity.
CH3CH2CH2NH2 Propane-1-amine is often named as Propamine.
ClCH2CH2OH 2-Chloroethan-1-ol is often named as 2-Chloroethanol
CH3CH2CH2CHO Butan-1-al is often named as 2-Chloroethanol.
There are two types of prefixes:
1) Primary prefix : A primary prefix is used simply to distinguish cyclic from acyclic compounds.
For ex: In case of carbocyclic compounds, a primary prefix ,cyclo is used immediately before the word root.
Cyclo(Primary prefix) + Pent (word root) + ane( Primary suffix)
2) secondary prefix : Certain groups are not considered as functional groups but instead are treated as substituents. These are called secondary prefixes and are added immediately before the word roots in alphabetical order to denote the side chain or substituent groups.
The secondary prefixes for some groups which are always treated as substituent group are given below:
|Substituent Group||Secondary group||Substituent Group||Secondary Prefix|
IUPAC name of an organic compound consist of:
Secondary prefix+ Primary prefix+ Primary suffix+ Secondary Suffix
|Organic compound||Secondary Prefix||Word Root||Primary Suffix||IUPAC name|